e-ISSN : 0975-4024 p-ISSN : 2319-8613   
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ABSTRACT

ISSN: 0975-4024

Title : Electrochemical Behaviors of Graphite in an Ethylene Carbonate-Based Electrolyte Containing Two Different Types of Film-Forming Additive
Authors : Sa Rang Yoon, Soon-Ki Jeong
Keywords : graphite electrode; surface film; additive; vinylene carbonate; fluoroethylene carbonate; litihum bis(oxalato)borate; lithium-ion battery
Issue Date : Apr-May 2016
Abstract :
Electrochemical reactions occurring at a graphite electrode were investigated to gain insight into the effects of film-forming additives such as vinylene carbonate, fluoroethlyene carbonate (FEC) and lithium bis(oxalato) borate (LiBOB) on surface film formation on the electrode. The surface film generated in the presence of a mixture of FEC and LiBOB was found to have the certain characteristics that are important in the initial charging and discharging process. The mixture produced a highly resistive film on the graphite electrode, resulting in an improvement in Coulombic efficiency.
Page(s) : 1032-1038
ISSN : 0975-4024
Source : Vol. 8, No.2